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Study of the influence of structure on the resistivity of silicate composites
Uher, Vojtěch ; Šteffan,, Pavel (referee) ; Drochytka, Rostislav (advisor)
Electroconductive silicate-based composites are advanced materials that allow building structures to perform several different functions simultaneously. Addressing the issues of their development and use is a suitable topic for research work. The aim of this work is to study the effect of structure on the resistivity of silicate composite. The structure of electrically conductive composites is studied on dry cement paste and mortar mixtures as well as on test bodies made of hardened cement paste and mortar after 28 days of curing. Based on the analysis of the raw materials, six suitable electroconductive fillers are selected based on particle size, resistivity, and water absorption. The parameters of dry cement paste and hardened cement paste with replacement of 4-19 wt. % cement by the selected fillers are determined. Two of the fillers are selected for use in dry and hardened mortar. Resistivity is determined for all dry mixes and hardened composites variants, and percolation thresholds are approximately determined. By studying the structure of the selected variants, it is shown that the most important parameters that have the greatest influence on the resistivity of the silicate composites are mainly the particle size and the intrinsic resistivity of the electrically conductive filler. For silicate composites in the hardened state, the volume of hydration products, especially portlandite and C-S-H gels, also has a significant influence. For both dry blends and hardened composites, it was found that the smaller the particle size of the electroconductive filler, the smaller the representation needed to reach the percolation threshold. Portlandite and C-S-H gels in the volume of the hardened composite cause its high resistivity. The resistivity of the hardened composite is always higher than that of the dry blends. Thus, the proportion of electroconductive filler needed to reach the percolation threshold is higher in hardened composites than in dry mixes. The resist
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Study of the influence of structure on the resistivity of silicate composites
Uher, Vojtěch ; Šteffan,, Pavel (referee) ; Drochytka, Rostislav (advisor)
Electroconductive silicate-based composites are advanced materials that allow building structures to perform several different functions simultaneously. Addressing the issues of their development and use is a suitable topic for research work. The aim of this work is to study the effect of structure on the resistivity of silicate composite. The structure of electrically conductive composites is studied on dry cement paste and mortar mixtures as well as on test bodies made of hardened cement paste and mortar after 28 days of curing. Based on the analysis of the raw materials, six suitable electroconductive fillers are selected based on particle size, resistivity, and water absorption. The parameters of dry cement paste and hardened cement paste with replacement of 4-19 wt. % cement by the selected fillers are determined. Two of the fillers are selected for use in dry and hardened mortar. Resistivity is determined for all dry mixes and hardened composites variants, and percolation thresholds are approximately determined. By studying the structure of the selected variants, it is shown that the most important parameters that have the greatest influence on the resistivity of the silicate composites are mainly the particle size and the intrinsic resistivity of the electrically conductive filler. For silicate composites in the hardened state, the volume of hydration products, especially portlandite and C-S-H gels, also has a significant influence. For both dry blends and hardened composites, it was found that the smaller the particle size of the electroconductive filler, the smaller the representation needed to reach the percolation threshold. Portlandite and C-S-H gels in the volume of the hardened composite cause its high resistivity. The resistivity of the hardened composite is always higher than that of the dry blends. Thus, the proportion of electroconductive filler needed to reach the percolation threshold is higher in hardened composites than in dry mixes. The resist
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